Postgraduate
MA in conservation of wall painting
RESEARCH PROJECTS
Scientific examination of the Roman and early Byzantine wall paintings of Caesarea, Israel
(in collaboration with and sponsored by the ISRAEL
ANTIQUITIES AUTHORITY)
Ravit Linn
Summary
The aim of this study was to investigate
the original materials and techniques used in the Roman and the Byzantine wall
paintings of Caesarea. In addition, it was intended that such a study should
contribute to the conservation of these paintings, since an understanding of
the nature of the materials is essential for assessing their current condition
and their susceptibility to future deterioration.
The recent excavations in Caesarea have revealed many interesting
wall paintings, some of which are unique for the area, such
as the 'Animals'
scheme in the Roman hippodrome and the early Byzantine paintings
with Christian iconography in the vaults complex.
The study involved an initial period of collection of archaeological and conservation documentation, and then in-situ examination of all the paintings. Based on this, thirteen of the twenty-eight schemes of painting were selected for detailed investigation and scientific analysis.
Various techniques were used for the examination and analysis, including polarised light microscopy (PLM), micro-chemical testing (MCT), scanning electron microscopy with an energy dispersive x-ray analysis (SEM-EDX), x-ray diffraction (XRD), and Fourier transform infrared microspectroscopy (FTIR).
As anticipated, there were some very interesting results.
The range of pigments found was extensive, including red lake,
cinnabar, malachite, and possibly ultramarine, as well as the
more common pigments: calcium carbonate white, haematite, red
and yellow ochre, green earth, Egyptian blue and carbon black.
From this palette Caesarea's painters produced an extremely
wide range of hues and tones, both by mixing and layering the
various pigments.
It is presumed that most of the paintings were executed in
lime-based techniques, though some of the materials, such as
red lake and cinnabar, would have been bound with an organic
medium. Although the plasters are all lime-based, there is
a particularly wide range of aggregate types, mixing ratios,
and application methods, including polishing. In most instances,
the aggregates were identified as local materials, typically
from the shore gravel including mainly quartz sand, calcareous
sandstone and bioclasts. Plasters with crushed calcite occur,
and reflect the practice described by Vitruvius. Crushed ceramic
material (as well as large sherds) was used, and it seems likely
that the plaster for the Byzantine nymphaeum was hydraulic.

Several aspects of the original technique were observed to
have a direct bearing on conservation issues: for example,
the preferential deterioration of white in Roman painting;
the susceptibility to erosion of plasters with large aggregates
in the final plaster layer; and, quite significantly, the occurrence
of pigments subject to photodeterioration such as red lake
and cinnabar.
September 1996
